Modern Coordination Chemistry: The Legacy of Joseph Chatt

Front Cover
G. J. Leigh, N. Winterton
Royal Society of Chemistry, 2002 - Science - 386 pages
Joseph Chatt was a pioneering figure in coordination chemistry. Intended as a record of Chatt's life, work, and influence, this book begins with a description of Chatt's career presented by co-workers, contemporaries, and students, then goes on to show that many of today's leading practitioners in the field have been influenced by Chatt. The latest research in coordination chemistry is presented to highlight Chatt's continuing legacy, in sections on the synthesis and reactivity of hydrido and dihydrogen complexes, the chemistry of phosphines, transition metal complexes of olefins and related isolobal ligands, chemistry related to dinitrogen complexes, the biological work of the ARC unit of nitrogen fixation at the University of Sussex, and patterns and generalizations in stability and reactivity. Leigh is affiliated with the University of Sussex, UK, and Winterton is affiliated with the University of Liverpool, UK. The book is distributed in the US by Springer Verlag. Annotation copyrighted by Book News Inc., Portland, OR.
 

Contents

A Memorable Start to a Career
8
Recollections of Life with Joseph Chatt at The Frythe
18
Some Memories of his Work at The Akers
25
Hydrides Hydrogen Bonding and Dihydrogen Activation
31
Intermodular Interactions
37
Ruthenium Hydride and Dihydrogen Complexes
47
RuH2H2PCy32
53
Hydrido Complexes of Group 6 Transition Metals
59
Trying to Cleave the NN Bond
194
MetalDinitrogen Chemistry after Chatt
198
Acknowledgements
206
Concluding Remarks
215
Polydentate NS Donor Ligands
223
Conclusions
229
The Biological Work of the ARC Unit of Nitrogen Fixation
231
Biochemical Research
238

References
65
Discussion
72
References
78
Background
80
References
87
Mechanistic in situ Homogeneous Catalytic Studies
95
Transition Metal Complexes of Olefins Acetylenes Arenes
101
Addendum
108
Olefin Complexes versus Metallacyclopropane
115
Acknowledgements
121
Cycloaddition Reactions with MetalIal3Dipoles
123
Acknowledgements
137
Exploiting the Isolobal Relationship between
144
Acknowledgements
152
Synthesis of Ruthenium Rhodium Heterobimetal
155
Conclusion
161
Acknowledgements
167
The Search for Reactions of Coordinated Dinitrogen
173
Formation of Amines
180
Dinitrogen Activation by Early Transition Metal
187
Genetical Research
246
Vanadium Molybdenum and Iron Complexes Based on
252
Acknowledgements
261
The Nature of Molybdenum and Tungsten Centres
263
Chemistry Related to that of the Catalytic Centres
269
Acknowledgements
275
IronImide Cluster Chemistry
281
Determinants of the Reduction Potential in Rubredoxins
288
The Solvation Energy Term U
294
Acknowledgement
300
Patterns and Generalisations in Stability and Reactivity
303
Chemical Hardness
309
Collaborative Research with Chatt on the Kinetic
321
Tuning Rhodiuml Metal Centre Accessibility in Iodomethane
328
Other Papers Presented at the 34th International Conference
341
Energydependent Electrospray Tandem Mass
347
References
353
Late Transition Metals
359
A Rational Design of Heteropolynuclear Squarate
366
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