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Such is the constitution of these two compounds of phosphorus and hydrogen as taught by our systematists, and confirmed to apparent demonstration by Dr. Thomson in his First Principles of Chemistry, I. 203. But it is to be feared that the atomic theory, misapplied, has here acted as a false light merely to mislead from the straight path of experiment. For M. Dumas in an able memoir has adduced very decisive evidence of the inaccuracy of the above views, and has been led to conclude that protophosphureted and perphosphureted hydrogen contain each the same bulk of hydrogen, that is, 1 time their own volume; that the quantities of phosphorus with which that hydrogen is combined in the two gases are not in the ratio of 1 to 2, but of 2 to 3; that the ratio of 3 to 5 instead of 1 to 2, holds with regard to the oxygen in phosphorous and phosphoric acids, agreeably to the well known determination of Berzelius; and finally that the gases obtained by heating phosphorous acid, or by leaving perphosphureted hydrogen over water or mercury for a few days, are not different in their nature, but truly identical. We therefore present the results of M. Dumas in a supplementary form, whence they may be compared with those latterly adopted in this country.

1. Protophosphureted hydrogen. This gas may be obtained perfectly pure by heating the phosphatic, phosphorous, or hypophosphorous acids, or by admitting fragments of phosphuret of lime or barytes to concentrated muriatic acid. But the gas disengaged from phosphuret of lime by water alone, or by muriatic acid diluted with ten times its weight of water, consists in the former case of perphosphureted hydrogen 87 + hydrogen 13; and in the latter of perphosphureted hydrogen 97 water 7. Protophosphureted hydrogen is not spontaneously combustible in air, as the other gas is. 100 measures of protophosphureted hydrogen, heated with bichloride of mercury, afford 300 measures of muriatic acid gas, which contain 150 of hydrogen. But, when 100 measures of that phosphureted gas are heated in contact with sulphur, only 135 measures of sulphureted hydrogen are obtained instead of 150; because 100 of sulphureted hydrogen become ninety by being heated with sulphur; and 90: 100:: 135: 150. From inattention to this important fact, several analytical errors have arisen. The detonation of protophosphureted hydrogen mixed with oxygen is elegantly effected by a slight difference of pressure by raising for instance the eudiometer tube a few inches above the level of the mercury. If this circumstance be not adverted to, unexpected explosions may occur.

One volume of protophosphureted hydrogen gas absorbs in explosion two volumes of oxygen; and, as the volume and a half of hydrogen which it contains requires three-fourths of a volume of oxygen, the remaining five-fourths of a volume of oxygen must go to the phosphoOne volume of this phosphureted gas may also combine with a volume and a half of

rus.

oxygen, in which case phosphorous a
ed with the three-fourths of oxyg
phosphoric acid was the former produce
five-fourths of oxygen. Thus it wo
that the quantities of oxygen in phos
phosphoric acids are to each other,
portion of 3 to 5. The perphosphere
gen procured by the action of phot
milk of lime is spontaneously tran
keeping over water to the protop
gas, without experiencing any alter
volume, simply by depositing phosph
proportion of pure hydrogen which t
present in the perphosphureted a
of course remains mixed with the pr
phureted, is easily ascertained by s
sulphate of copper, which speedily as
phosphureted gas. Protophosphuree
prepared and examined was weighed
the requisite precautions, and found i
specific gravity of 1-214, air being 1
ducting from 1.214, 0·104 (
0.0694,

2

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), being a volume and a half of b the remainder 1.110 is the weight of pr combined in this gas with the 0-104 of y Now this is nearly the ratio of 10 to 1; if we were to consider it a compound! atom of each constituent, the prime of phosphorus would come out 1078 hydrogen scale, or 14 on the oxygen. mas, who adopts, with Berzelius, 00€. atom of hydrogen and the radix weights, supposes that in the protoples as six atoms of hydrogen are combine one of phosphorus, and infers the equa phosphorus to be 402-3: for,

0.103 1111: 37·4 (= 6 H): 4%. The number of Berzelius is 392-3; them Dumas proposes to assume 400, the sam Dulong fixed on from the analyses of ride of phosphorus and phosphuret of

Ca

gases

and t

2. Perphosphureted hydrogen. This tained by acting on phosphorus in a re a boiling-hot solution of caustic potassa, very uniformly of thirty-seven and a perphosphureted gas, mixed with sixty-t half of pure hydrogen; or of three former to five of the latter. The phos gas is easily abstracted by a solution of or nitrate of copper, or of corrosive Phosphuret of barytes disengages from water a mixed gas, consisting of fortypure hydrogen, and fifty-seven of the p phureted gas. Phosphuret of lime, acted a little water over mercury, affords a mixture of gases, of which eighty-sever perphosphureted, and thirteen pure hyd The same substance, acted on by strong atic acid, affords protophosphureted by with deposition of phosphorus. The pe phureted hydrogen obtained by boiling lime on phosphorus is most variable in pr portion of intermingled hydrogen; this near the beginning of the process per cent., and towards the end so high as six. Yet all these gases are equally infan ble in the air.

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PHOSPHURETED HYDROGEN.

sive sublimate acts on the above mixed "it does on protophosphureted hydrogen, hydrogen gas intermingled remains pure, combining with the chlorine, at least at of the alcohol flame. The action of the e sublimate becomes energetic whenever The gas enlarges much in volume, Dorange-brown matter is produced. Se: six parts of the mixed gas, containing even and a half of pure hydrogen and -eight and a half of perphosphureted gas, ted eighty-six of muriatic acid gas, conforty-three of hydrogen; whence perhureted hydrogen evidently contains a e and a half of pure hydrogen condensed ›ne volume, just like the protophosphureted The gas from phosphuret of lime and , which is the purest that can be obtained, ded also, by a similar treatment, three mes of muriatic acid gas for every volume e pure perphosphureted hydrogen, indicatne volume and a half of pure hydrogen coned in that single volume. The mixed gas phosphuret of lime and water contains eleven to twelve per cent. of uncombined -ogen. Such mixed gas, heated by a spirit e, in contact with fine iron or copper wire in ass vessel, affords out of every volume of the phosphureted gas one volume and a half of ⚫ hydrogen.

257

phureted gas by oxygen, M. Dumas prepared
absolutely pure carbonic acid. Some of it he
mixed with its own volume of pure oxygen;
and some with variable proportions of perphos-
phureted hydrogen obtained from potassa w ter
and phosphorus. He then heated the mixture of
carbonic acid gas and oxygen to 212° or 230°
Fahrenheit, and introduced into it by bubble
after bubble the mixture of carbonic acid and
perphosphureted hydrogen. With these precau-
tions the experiment proceeded quietly; each
bubble exploded on entering, however minute it
might be. The light was faint and yellowish,
without the lustre and vivacity observed in the
ordinary combustions of this kind. When the
operation was completed, he absorbed the car-
bonic acid by moist fragments of caustic potassa
used in excess, and measured carefully the resi-
duum, ascertaining the purity of the residual
oxygen by explosion with hydrogen in the eudi-
ometer over mercury.
From the mean of these
experiments, it results that 151 measures of
perphosphureted hydrogen, produced by the
action of phosphorus on water of potassa, con-
sume 152 measures of oxygen; which may be
regarded as the ratio of volume to volume. But
this ratio, so simple in appearance, becomes
somewhat complex when we come to consign, to
each of the bodies that the perphosphureted hy-
drogen contains, the portion of oxygen due to it.
In fact,

In order to effect the analysis of the perphos-
8 measures of the above gas 5 hydrogen + 3 perphosphureted hydrogen

8

Oxygen 2.5

it is to say, three volumes of pure perphosreted hydrogen consume 5.5 volumes of 8 perphosphureted hydrogen pure 14.6 oxygen

It is therefore evident that, in the combustion perphosphureted hydrogen made under the Dove specified conditions, the hydrogen takes vo volumes of oxygen and the phosphorus three, > form water and phosphorous acid. Perphosphureted hydrogen gas, left to itself or some days, loses a third of the phosphorus hat it contains, passing to the state of protophoshureted hydrogen without any change of voume. When the perphosphureted hydrogen is lecomposed by the protoxide of azote, eight volumes of the former consume twenty-one of the oxygen of the latter, six of which go to the twelve of hydrogen in the eight of the perphosphureted gas, and fifteen to the phosphorus. In this case phosphoric acid is formed. Hence the same quantity of phosphorus takes either nine or fifteen volumes of oxygen; which gives the relation of three to five, formerly noticed. The explosion of protoxide of azote and perphosphureted hydrogen is extremely violent, and ought on this account to be performed on small quantities. The specific gravity of perphosphureted hydrogen, determined by M. Dumas with much care, was found to be

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1.761

from which if we deduct 1 vol. of hydr. 0.104 we shall have the remainder. 1.657

for phosphorus. Here the proportion reduced to hydrogen as unity is sixteen to one. M. Dumas, supposing the hydrogen and the phosphorus VOL. XVII.

+ 5.5.

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12.5

100, and hydrogen 6·2175, or nearly 2

In this ingenious and elaborate research of M. Dumas, nothing is more striking than the difference between his specific gravities of these two gases and the densities assigned to the same gases in Dr. Thomson's First Principles, where every number, by a process of logical legerdemain, is made to tally with his atomic notions to the third or fourth place of decimals. Thus his gas (perphosphureted hydrogen) from phosphuret of lime and water has a specific gravity of 0.90277; and is thus made upHydrogen, 1 volume 0.06944 or 1 atom 0-125 Phosphorus, 1 do. 0-83333 1

0-90277

1-5!

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Here this gas is made to contain two volumes of hydrogen, and have a density = 0·9722.

Phosphorus and sulphur are capable of combining. They may be united by melting them together in a tube exhausted of air, or under water. In this last case they must be used in small quantities; as, at the moment of their action, water is decomposed, sometimes with explosions. They unite in many proportions. The most fusible compound is that of one and a half of sulphur to two of phosphorus. This remains liquid at 40° Fahrenheit. When solid, its color is yellowish-white. It is more combustible than phosphorus, and distils undecompounded at a strong heat. Had it consisted of 2 sulphur + 4 phosphorus, we should have had a definite compound of 1 prime of the first + 1 of the second constituent. This proportion forms the best composition for phosphoric fire-matches or bottles. A particle of it attached to a brimstone match inflames when gently rubbed against a surface of cork or wood. An oxide made by heating phosphorus in a narrow-mouthed phial with an ignited wire answers the same purpose. The phial must be kept closely corked, otherwise phosphorous acid is speedily formed.

Phosphorus is soluble in oils, and communicates to them the property of appearing luminous in the dark. Alcohol and ether also dissolve it, but more sparingly.

When swallowed in the quantity of a grain it acts as a poison. Azote dissolves a little of it, and has its volume enlarged by about one-fortieth.

PHOTINIANS, in ecclesiastical history, a sect of heretics in the fourth century, who denied the divinity of our Lord. They derive their name from

PHOTINUS, their founder, who was bishop of Sirmium, and a disciple of Marcellus. Photinus published, in the year 343, his notions respecting the Deity, which were repugnant both to the orthodox and Arian systems. He asserted that Jesus Christ was born of the Holy Ghost and the Virgin Mary; that a certain divine emanation, which he called the Word, descended upon him; and that because of the union of the divine word with his human nature he was called the Son of God, and even God himself: that the Holy Ghost was not a person, but merely a celestial virtue proceeding from the Deity. Both parties condemned the bishop in the councils of Antioch and Milan, held in the years 345 and 347. He was condemned also by the council at Sirmium in 351, and was afterwards degraded from the episcopal dignity, and at last died in exile in the year 372 or 375. His opinions were afterwards revived by Socinus.

PHOTIUS, patriarch of Constantinople, was one of the finest geniuses of his time. He was born in Constantinople, and descended of a noble family. His merit raised him to the patriarchate; for, Bardas having driven Ignatius from the see, Photius was consecrated by Asbestus in 859. He condemned Ignatius in a synod, whereupon the pope excommunicated him, and he, to balance the account, anathematised the pope. Basilius of Macedon, the emperor whom Photius had reproved for the murder of Michael, ex

pelled him, and restored Ignatius; but afterwa re-established Photius upon Ignatius's dean, . 878. At last being wrongfully accused of conspiracy against Leo the philosopher, son z. successor to Basilius, he was expelled by h 886, and died soon after. He wrote a Btheca, which contains an examen of 280 a also 253 epistles; the Nomacanon under teen titles; an abridgment of the acts of ser councils, &c. His natural abilities were r great. There was no branch of art or sciens. which he was not versed. He was first raise the chief dignities of the empire, being a principal secretary of state, captain of the r and a senator; and in all these stations acqu himself well. His rise to the patriarchister very quick; for, being a layman, he was t monk the first day, reader the next, and the lowing day sub-deacon, deacon, and priest that in six days he attained to the highest of the church. But his unbounded ambition him commit excesses which rendered hi scourge to those about him. Fabricius cas Bibliotheca, non liber, sed insignis thes not a book, but an illustrious treasure, in v are contained many curious things no where to be found. It was brought to light by A Schotus, and communicated by him to ex Hoeschelius, who caused it to be prim 1601. Schottus translated it into Lat, El printed his translation alone in 1600 7 Greek text and translation were printed neva in 1611. The last and best editio printed at Rouen in 1653, folio.

PHOTOCITE, a mixture of the silicate carbo-silicate of manganese.

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PHOTOMETER, an apparatus for e suring the intensity of light, and the transpar of the medium through which it passes. ments for this purpose have been invented count Rumford, M. de Saussure, Mr. Lesb others. Mr. Leslie's is the simplest instr of the kind, but it only measures the moters intensities of light; and a description of 2 them would take up too much room. Wether refer the inquisitive reader to Nicholson's sophical Journal, vol. iii. De Saussure's meter is also called a diaphanometer. Mr.Le photometer may be considered as a dife thermometer, having one of its balls of cat glass, the other of black glass. The lig duces no effect upon the transparent ba heats the black ball according to its ine and this heat, by depressing the liquid tube, marks the intensity of the light.

PHOTOPSIA (from owe, light, and w vision), lucid vision. An affection of the eye which the patient perceives luminous rays, ig lines, or coruscations.

PHOXUS, a general of the Phocæans, burnt Lampsacus.

PHRAGANDE, an ancient people of Thrax. Livy, xxvi. c. 25.

PHRAORTES, the son of Dejoces, and te second king of the Medes, succeeded his fat about A. Å. C. 657, and reigned twentyyears. He was killed in a fruitless attemp Nineveh, and was succeeded by his son Cyas

ares I.

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The scholars of Ireland seem not to have the least

conception of a stile, but run on in a flat phraseology, often mingled with barbarous terms. Swift.

Precision is the third requisite of perspicuity with respect to words and phrases. Murray.

PHRASE is sometimes used for a short sentence or small set or circuit of words constructed together. In this sense father Buffier divides phrases into complete and incomplete. Phrases are complete where there is a noun and a verb, each in its proper function; i. e. where the noun expresses a subject, and the verb the thing affirmed of it. Incomplete phrases are those where the noun and the verb together only do the office of a noun; consisting of several words without affirming any thing, and which might be expressed in a single word. Thus, that which is true,' is an incomplete phrase, which might be expressed in one word, truth; as, that which is true satisfies the mind,' i. e. 'truth satisfies the mind.'

PHRASE, in music, means a complete sense composed of one or more musical propositions, terminated by a cadence more or less complete. In a phrase there may be various significations or ideas, viz. the principal, which commences and terminates the phrase, the expletives, incidents, oblique or subordinate. To phrase is to round, as in discourse, the different phrases of a musical period. Music, without phrases, called

also hemistics, is sound without sense, whether in its composition or performance.

PHRASE, OF PHRASED, a musical composition performed upon the principle of hemistics, or whose melodic phrases are rounded off.

PHRASEOLOGY is also used for a collection of the phrases or elegant expressions in any lan

guage.

PHREAS (John), M. D., an English physician, born at London in the end of the fourteenth century. He was educated at Oxford, and became fellow of Baliol College. He translated from the Greek into Latin Diodorus Siculus, and other ancient works. He read lectures on medicine at Ferrara, Florence, and Padua, at which last university he was presented with his degree. He died in 1465.

απ

PHREATIS, or PHREATIUM, in Grecian antiquity, was a court belonging to the civil government of Athens, situated upon the sea-shore in the Piræus. The name is derived from ano re ppearos, because it stood in a pit; or, as others suppose, from the hero Phreatus. This court heard such causes as concerned persons who had fled out of their own country for murder, or those who fled for involuntary homicide, and who had afterwards committed a deliberate and wilful murder. The first who was tried in this place was Teucer, on a groundless suspicion that he had been accessory to the death of Ajax. The accused was not allowed to come to land, or so much as to cast anchor, but pleaded his cause in his bark; and if found guilty was committed to the mercy of the winds and waves, or, as some say, suffered more condign punishment; if innocent he was only cleared of the second fact, and, according to custom, underwent a twelvemonth's banishment for the former. See Potter's Gr. Antiquities, vol. i.

PHRENETIC is used of those who, without being absolutely mad, are subject to such strong sallies of imagination as in some measure pervert their judgment and cause them to act in a way different from the more rational part of mankind.

PHRENITIS is the same with phrenzy ; an inflammation of the brain, attended with an acute fever and delirium. See MEDICINE.

PHRENOLOGY.

PHRENOLOGY (of Gr. pony the mind, and Moyos, a discourse), denotes strictly the science of mind, and has recently been applied to a new theory of philosophy, which teaches

1. That the brain is à congeries of so many distinct parts, each of which is the organ of some innate special faculty.

2. That the power of manifesting each faculty is always proportionate to the size and activity of that organ or part of the brain with which it is supposed to be in immediate connexion.

3. That it is possible to ascertain, during life, the relative sizes of these organs by the corresponding protuberances or enlargements on the external surface of the cranium.

In our article BRAIN it is suggested that the term phrenology, in application to the hypothesis,

the legitimacy of which is now to be discussed, seems too presumptive and too restrictive-too presumptive in implying or taking for granted that this is the true science of mind; and too restrictive, because the phrenic or mental part of the argument does not comprehend its whole scope and bearing; the system of Gall and Spurzheim (the principal founders and promulgators of it), constituting, when taken in its full stretch of latitude, in some sort a new system of neurology in general.' But Dr. Spurzheim, who we believe was the first to propose the present denomination, might have been guided in his choice by an anxiety which he and his original master, Gall, have ever manifested to scout the idea of their doctrines being, as some have supposed them to be, merely a new system of phy

siognomy. Denude,' says Dr. S., 'the whole of the brain, and present it to me without any cranial covering, and I will pledge myself to as correct an opinion of its phrenological character, as had I to judge of the same brain, surrounded and encompassed by its membraneous and bony investments.' Craniology, therefore, is an improper appellation to give to our science; and cranioscopy is obviously as bad, since they both suppose a knowledge only of the exterior, while our investigations and our inferences have to do with what is within much more than what is merely on the surface, or manifest to every beholder. Our anatomy is new, our physiology is new, our metaphysics are new; or rather, in reference to the last, we should say, that metaphysics has hitherto been a science merely in name, since it has abandoned physicology, and taught to satisfy itself with mere abstractions.

Our present duty is that of historians and narrators. If in the course of the present article a bearing to one side of the argument be discovered, let the reader be told that some twelve or fourteen years since, when Dr. Spurzheim's book first made its appearance, the individual who principally supplies this article furnished a review of Dr. S.'s voiume, which all would agree in pronouncing rather condemnatory than in support of the doctrine. See Eclectic Review, 1815. Whether he still preserve his originally hostile feeling to the cause, or whether he be completely indifferent respecting the subject, and pretended science, is for any reader to determine who may think it worth his while to bestow an hour's consideration on the topic. All that we think it right further to say in the way of preface is this, that impartiality shall at any rate be aimed at, and that failure shall not be legitimately chargeable upon design or intention. It may be proper to remind the reader too, that, although the plural pronoun is used in the construction of the paper, as is usual in all articles admitted into a miscellaneous collection, neither the editor, or other contributors, are responsible for the opinions of individual writers on subjects open to controversy.

We cannot perhaps give a more convincing proof of our impartial feeling than by freely extracting from able writers, who have taken different estimates of the validity of this doctrine. The first of them, an acute reasoner, is decidedly hostile to its claims.

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tute the system. Have not the phrense like the aspiring giants of the olden tie, piled Mount Ossa on Pelion, and Pes Olympus, crowded organ upon organ fret base to the vertex of the head? Have not supposed relative positions and dimensi these, as indicated by isolated protubers been taught in books, lectures, and delinea all the phrenological busts? Have they pretended to measure them severally and vidually in living characters even to the eg an inch? But this is not all. In adverting custom which different nations have of comp ing and otherwise changing the form of the b Dr. Spurzheim remarked-The instrumen 2) is worn for this purpose has been brough England; I know not exactly how long i been used, but have heard about two years is curious and worthy investigation, and I w have you, should any of you have the opportu make this enquiry, see, when the bone is t pressed, whether the brain underneath it to increase in size. You may try it in a for, if it be the case, then we could in it compress the head in its different parts, a give a direction and development to the bet noblest facts of the human mind.”—MS. e of lectures, delivered in Edinburgh in 18%

'How beautiful,' says Mr. S., is this tion! How characteristic of the philos all the phrenological speculations! Whe annus mirabilis comes to pass it will bea millennium of phrenology. We shall the deed, hear no more of little lumps and p berances,' but shall speak of the mount veneration being bounded on the south by valley of amativeness, and on the east and by the caverns of destructiveness. The idea public of Plato, the Atalantis of Harrison, Utopia of More, were all only dim and conceptions of that state of perfectibility of wh the human mind and heart are thus suppo susceptible.'

In another part of the pamphlet from whe we have borrowed this spirited extract we find most eloquent appeal against the phrenolo tenets grounded on the assumption that nat circumstances, the force of example, and varieties of creeds, have much more to do the excitement and manifestation of passion have the physical construction, whether de head or any other part of the frame. We re that we can only extract a part of this pass

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The organ of destructiveness, only termed that of murder, is considered by the pre nologists as having been completely establishe Dr. yet the manifestation of the feelings attributed w this faculty will invariably be found to res from those external circumstances and m causes which alone appear to determine all the darker, as well as the brighter, traits of human character.'

Neither in man nor in animals,' says Mr. Stone, is it possible to ascertain during life the relative positions and sizes of those organs to which each of the more favored faculties has been assigned a local habitation and a name.' Spurzheim has lately observed, We do not judge by the particular elevations and lumps upon the skull, but by its general development. Our adversaries are the bumpists-but no, look at the general appearance-judge for yourselves (MS. notes of lectures on the anatomy, physiology, and pathology of the brain, delivered in Edinburgh, 1828). What,' continues Mr. Stone, Dr. Spurzheim would have us to understand by this declaration, it is impossible to comprehend; for in the same course, nay, in the same lecture, he proceeded to demonstrate the individual bumps and protuberances which in fact consti

"The duty of vengeance is held to be impera tive among the North American Indians. The instance is related by a traveller of a young Choc taw, who, having been reproved by his mother,

took it so ill as, in the fury of his shame, tore solve on his own death." He committed suicide, and his sister, being his nearest relation and thinking herself bound to revenge his loss, told

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